Manolo Santana Stadium – Ora italiana: 13:30 (ora locale: 1:30 pm)
1. [3] Gabriela Dabrowski / Demi Schuurs vs [2] Barbora Krejcikova / Katerina Siniakova
2. [5] Alexander Zverev vs [3] Dominic Thiem (non prima ore: 16:00)
3. [1] Ashleigh Barty vs [5] Aryna Sabalenka (non prima ore: 18:30)
4. Casper Ruud vs [8] Matteo Berrettini (non prima ore: 21:00)
Arantxa Sanchez Stadium – Ora italiana: 14:00 (ora locale: 2:00 pm)
1. Sander Gille / Joran Vliegen vs [2] Nikola Mektic / Mate Pavic
2. Tim Puetz / Alexander Zverev vs [3] Marcel Granollers / Horacio Zeballos
